BIODIESEL PRODUCTION FROM WASTE COOKING OIL BY USING ULTRASONIC TUBULAR REACTOR
DOI:
https://doi.org/10.22441/ijimeam.v2i1.18955Kata Kunci:
Ultrasonic tubular reactor, biodiesel, waste cooking oil, Sonochemistry, cavitation, transesterificationAbstrak
The aim of this research is to find an optimum of synthesis biodiesel from waste cooking oil (WCO) using ultrasonic tubular reactor. The experimental studies explored the variations in reaction time, molar ratio WCO to methanol (MeOH), amount of catalyst, frequency of ultrasonic and output power ultrasonic on the ester contents. Comparisons of type ultrasonic and also mechanical stirring method based on time reaction were investigated. The optimum results of biodiesel process is the reaction time of 5 minute, NaOH catalyst 1%wt of WCO, molar ratio WCO to MeOH of 1:6, frequency ultrasonic of 20 KHz and output power ultrasonic of 650 W. The reaction time reduced 12-24 times compared to both of method and the yield of ester contents was obtained at 96.54%wt.Unduhan
Referensi
P.T. Vasudevan, & M. Briggs, Biodiesel production - current state of the art and challenges, J. Ind. Microbiol. 2008; 35:421-430.
R. Alcantara, J. Amores, L. Canoira, E. Fidalgo, M.J. Franco, & A. Navarro, Catalytic production of biodiesel from soy-bean oil, used frying oil and tallow, Biomass Bioenerg. 2000; 18: 515-527.
L.C. Meher, D. Vidyasagar, & S.N. Naik, Technical aspects of biodiesel production by transesterification – a review, Renew. Sust. Energy. Rev. 2006; 10: 248–268.
Malaysian Palm Oil Industry Performance 2008, Global Oils & Fats Business Magazine, 6 (2009) 1-4.
A. Demirbas, Economic and environmental impacts of the liquid biofuels, Energy Edu Sci Technol. 2008: 22; 37–58.
A. Johari, B.B Nyakuma, S. Husna. M.N, R. Mat, H. Hashim, A. Ahmad, Z.Y. Zakaria, & T.A.T Abdullah, The challenges and prospects of palm oil based in Malaysia, Energy. 2015; 81:255–261.
H. Duc, N. The, K. Okitsu, R. Nishimura, & Y. Maeda, Biodiesel production through transesterification of triolein with various alcohols in an ultrasonic field, Renew. Energy. 2009; 34: 766-768.
D. Kumar, G. Kumar, & C.P. Singh, Ultrasonics sonochemistry fast, easy ethanolysis of coconut oil for biodiesel production assisted by ultrasonication, Ultrason. Sonochem. 2010; 17: 555-559.
I. Choedkiatsakul, K. Ngaosuwon, G. Cravotto & S. Assabumrungrat. Biodiesel production from palm oil using combined mechanical stirred and ultrasonic reactor. Ultrason. Sonochem. 2014; 21: 1585-1591.
J. Ji, J. Wang, Y. Li, Y. Yu, & Z. Xu, Preparation of biodiesel with the help of ultrasonic and hydrodynamic cavitation, Ultrasonics. 2006; 44: 411–414.
A.K. Singh, S.D. Fernando, R. Hernandez, Base-catalyzed fast transesterification of soybean oil using ultrasonication, Energy Fuels.2007; 21: 1161–1164.
C. Stavarache, M. Vinatoru, R. Nishimura, & Y. Maeda, Fatty acids methyl esters from vegetable oil by means of ultrasonic energy, Ultrason. Sonochem. 2005; 12: 367-372.
J.A. Colucci, E.E. Borrero, & F. Alape, Biodiesel from an alkaline transesterification reaction of soybean oil using ultrasonic mixing, J. Am. Oil. Chem. Soc. 2005; 82: 525-530.
S.M. Hingu, P.R. Gogate, & V.K. Rathod, Ultrasonics sonochemistry synthesis of biodiesel from waste cooking oil using sonochemical reactors, Ultrason. Sonochemi. 2010; 17:827-832.
M. Maghami, S.M Sadrameli & B. Ghobadian, Production of biodiesel from fishmeal plant waste oil using ultrasonic and conventional methods, Applied Thermal Engineering. 2015; 75: 575-579.
G. Guoqing, N. Sakurai, & K. Kusakabe, Synthesis of biodiesel from sunflower oil at room temperature in the presence of various co-solvents. Chem. Eng. J. 2009;146: 302–306.
E. Westphal, L.H. Viana, R.G. Jacob, E.J. Lenarda, & M.G. Oca, Transesterification of castor oil assisted by microwave irradiation. Fuel. 2008; 87: 16-19.
H. Shahraki, M.H. Entezari & E.K. Goharshadi. Sono-synthesis of biodiesel from soybean oil by KF/γ-Al2O3 as a nano-solid-base catalyst. Ultrason. Sonochemi. 2015;23:266–274.
E.M. Usai, E. Gualdi, V. Solinas, & E. Battistel. Bioresource technology simultaneous enzymatic synthesis of FAME and triacetyl glycerol from triglycerides and methyl acetate. Bioresour. Technol. 2010; 101: 7707-7712.
D. Wen, H. Jiang, & K. Zhang. Review: Supercritical fluids technology for clean biofuel production. Progress in Natural Science. 2009; 19: 273-284.
T. G. Leighton, The Acoustic Bubble (Academic, London, 1994).
Y. Chongfu. Acoustic processing in liquids and accustic cavitation engineering. Appl Acoust (in Chinese), 2006; 25: 261 – 264.
K. Yasui. Effect of liquid temperature on sonoluminescence. J. Phys. Rev. E. 2001; 64: 016310.
K. Yasui. Temperature in multibubble sonoluminescence J. Chem. Phys. 2001; 115: 2893.
A.P. Vyas, J.L. Verma, & N. Subrahmanyam, Review article a review on FAME production processes, Fuel. 2010; 89: 1-9.
H. Mootabadi, B. Salamatinia, S. Bhatia, & A.Z. Abdullah, Ultrasonic-assisted biodiesel production process from palm oil using alkaline earth metal oxides as the heterogeneous catalysts, Fuel. 2010; 89: 1818-1825.
L.T. Thanh, K. Okitsu, Y. Sadanaga, N. Takenaka, Y. Maeda & H. Bandow, A two-step continues ultrasound assisted production of biodiesel fuel from waste cooking oils: A practical and economical approach to produce high quality biodiesel fuel. Biomass Techno. 2010; 101: 5394-5401.
M. Takase, W. Feng, W. Wang, X. Gu, Y. Zhu, T. Li, L. Yang & X. Wu. Silybum marianum oil as a new potential non-edible feedstock for biodiesel: A comparison of its production using conventional and ultrasonic assisted method. Fuel Processing Technology. 2014; 123: 19-26.
J.M. Encinar, J.F. González, E. Sabio, M.J. Ramiro, Preparation and properties of biodiesel from Cynara cardunculus L. oil, Industrial and Engineering Chemistry Research. 1999; 38: 2927–2931
U. Hoffmann, C. Horst, U. Wietelmann, S. Bandelin, & R. Jung, Sonochemistry, Ullmann’s Encyclopedia of Industrial Chemistry, sixth ed., Electronic Release, Wiley-VCH, Weinheim, Germany, 1999.
Y. Wang, S. Ou, P. Liu, F. Xue, & S. Tang, Comparison of two different process to synthesize biodiesel by waste cooking oil, J. Mol. Catal. A: Chem. 2006; 252: 107-112
H. Noureddini, D. Zhu, Kinetics of transesterification of soybean oil, J. Am. Oil Chem. Soc. 1997; 74: 1457–1463.
Manual book ultrasonic tubular reactor, Retrieved 28 January, 2014, from www.mpi-ultrasonics.com
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